TM 31-210
Improvised Munitions Handbook
| Section I |
No. 21 |
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PREPARATION OF PICRIC ACID FROM ASPIRIN |
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| Picric acid can be used as a booster explosive in detonators (Section VI, No. 13), a high explosive charge, or as an intermediate to preparing lead picrate (Section I, No. 20) or DDNP (Section I, No. 19). | |
| MATERIALS REQUIRED: | |
| Aspirin tablets (5 grams per tablet) | |
| Alcohol, 95% pure | |
| Sulfuric acid, concentrated, (battery acid - boil until white fumes appear) | |
| Potassium Nitrate (Section I, No. 2) | |
| Water | |
| Paper towels | |
| Canning jar, 1 pint | |
| Rod (glass or wood) | |
| Glass containers | |
| Ceramic or glass dish | |
| Cup | |
| Teaspoon | |
| Tablespoon | |
| Pan | |
| Heat Source | |
| Tape | |
| PROCEDURE: | |
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1. Crush 20 aspirin tablets in a glass container. Add 1
teaspoon of water and |
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2. Add approximately 1/3 to 1/2 cup of alcohol (100
milliliters) to the aspirin paste; stir while pouring. |
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3. Filter the alcohol-aspirin solution through a paper towel into another glass container. Discard the solid left on the paper towel. |
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4. Pour the filtered solution into a ceramic or glass dish. |
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5. Evaporate the alcohol and water from the solution by placing the dish into a pan of hot water. White powder will remain in the dish after evaporation. |
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NOTE: Water in pan should be at hot bath temperature, not boiling, approximately 160 to 180 degrees Fahrenheit. It should not burn the hands. |
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6. Pour 1/3 cup (80 milliliters) of concentrated sulfuric acid into a canning jar. Add the white powder to the sulfuric acid. |
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7. Heat canning jar of sulfuric acid in a pan of simmering hot water bath for 15 minutes; then remove jar from the bath. Solution will turn to a yellow-orange color. |
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8. Add 3 level teaspoons (15 grams) of potassium nitrate in three portions to the yellow-orange solution; stir vigorously during additions. Solution will turn red, and then back to a yellow-orange color. |
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9. Allow the solution to cool to ambient or room temperature while stirring occasionally. |
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10. Slowly pour the solution, while stirring, into 1-1/4 cup (300 milliliters) of cold water and allow to cool. |
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11. Filter the solution through a paper towel into a glass container. Light yellow particles will collect on the paper towel. |
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12. Wash the light yellow particles with 2 tablespoons (25 milliliters) of water. Discard the waste liquid in the container. |
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| 13. Place particles in ceramic dish and set in a hot water bath, as in step 5, for 2 hours. | |