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TM 31-210
Improvised Munitions Handbook


Section I

No. 21

PREPARATION OF PICRIC ACID FROM ASPIRIN

Picric acid can be used as a booster explosive in detonators (Section VI, No. 13), a high explosive charge, or as an intermediate to preparing lead picrate (Section I, No. 20) or DDNP (Section I, No. 19).



MATERIALS REQUIRED:
Aspirin tablets (5 grams per tablet)
Alcohol, 95% pure
Sulfuric acid, concentrated, (battery acid - boil until white fumes appear)
Potassium Nitrate (Section I, No. 2)
Water
Paper towels
Canning jar, 1 pint
Rod (glass or wood)
Glass containers
Ceramic or glass dish
Cup
Teaspoon
Tablespoon
Pan
Heat Source
Tape

 

PROCEDURE:

1. Crush 20 aspirin tablets in a glass container. Add 1 teaspoon of water and
work into a paste.

2. Add approximately 1/3 to 1/2 cup of alcohol (100 milliliters) to the aspirin paste; stir while pouring.

3. Filter the alcohol-aspirin solution through a paper towel into another glass container. Discard the solid left on the paper towel.

4. Pour the filtered solution into a ceramic or glass dish.

5. Evaporate the alcohol and water from the solution by placing the dish into a pan of hot water. White powder will remain in the dish after evaporation.

NOTE: Water in pan should be at hot bath temperature, not boiling, approximately 160 to 180 degrees Fahrenheit. It should not burn the hands.

6. Pour 1/3 cup (80 milliliters) of concentrated sulfuric acid into a canning jar. Add the white powder to the sulfuric acid.

7. Heat canning jar of sulfuric acid in a pan of simmering hot water bath for 15 minutes; then remove jar from the bath. Solution will turn to a yellow-orange color.

8. Add 3 level teaspoons (15 grams) of potassium nitrate in three portions to the yellow-orange solution; stir vigorously during additions. Solution will turn red, and then back to a yellow-orange color.

9. Allow the solution to cool to ambient or room temperature while stirring occasionally.

10. Slowly pour the solution, while stirring, into 1-1/4 cup (300 milliliters) of cold water and allow to cool.

11. Filter the solution through a paper towel into a glass container. Light yellow particles will collect on the paper towel.

12. Wash the light yellow particles with 2 tablespoons (25 milliliters) of water. Discard the waste liquid in the container.

13. Place particles in ceramic dish and set in a hot water bath, as in step 5, for 2 hours.

 


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